The spinel structures have a twined orientation and are controlled by close packed sheets.
2.
Spinel structures consist of multiple oxide structures that are cubic and have cubic close packing.
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Furthermore, at higher temperatures, the spinel structure is inherently unstable in the Li-based electrolytes used in Li-ion batteries.
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One of the more prominent compounds is, a lithium-manganese-oxide based material with a spinel structure ( space group Fd3m ).
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One main disadvantage of based batteries is that they suffer from lower overall capacities as a result of their spinel structure.
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A possible mechanism for the generation of deep-focus earthquakes is faulting caused by olivine undergoing a phase transition into a spinel structure.
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This hypothesis proposes that metastable olivine in oceanic lithosphere subducted to depths greater than 410 km undergoes a sudden phase transition to spinel structure.
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A possible mechanism for the generation of deep-focus earthquakes is faulting caused by olivine undergoing a phase transition into a spinel structure, with which they are believed to be associated.
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In addition to being a cheap and non-toxic alternative material, the spinel structure of provides a three-dimensional framework for the insertion and de-insertion of ions during discharge and charge of the battery.
10.
In order to explain the adoption of a particular cation distribution in a spinel structure, one must take into account the crystal field stabilization energies ( CFSE ) of the transition metals present.
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